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Home / Resources / Top 5 FDA-Approved Food-Grade Plastics

Top 5 FDA-Approved Food-Grade Plastics

June 23, 2021 by SyBridge Technologies

Originally published on fastradius.com on June 23, 2021

Plastic food packaging is essential for maintaining product freshness and quality in transport, prolonging shelf life, and meeting Food and Drug Administration (FDA) regulations. Plastics that come into contact with consumable products must adhere to FDA regulations and use materials guaranteed safe for use in plastic food packaging. This helps ensure consumer safety and protect your business from inadvertently breaking food safety laws.

When it comes to food safety, it’s best to play it safe. Design teams working in the food and beverage industries should know what the best food-safe plastic materials are to ensure products remain safe for consumers. Here’s everything you need to know about the top five FDA-approved plastics for food contact.

Acrylonitrile Butadiene Styrene (ABS)

ABS is an amorphous plastic created by combining acrylonitrile, butadiene, and styrene polymers. ABS is a food-grade plastic safe for use in food processing tools like food processors and refrigerator linings. Excellent resistance to strain and abrasion, maintained impact resistance at low temperatures, and insulating properties make ABS great for food transportation applications as well. This food-safe plastic is very flexible and can easily be welded to complex shapes, adding to its manufacturing diversity.

Parts built with ABS are aesthetically pleasing and stand up well to applications that aren’t in extreme temperatures. However, ABS components are also prone to stress cracking due to ABS’s poor weathering and solvent resistance.

High-Density Polyethylene (HDPE)

HDPE is a thermoplastic often used in milk jugs, plastic water bottles, cutting boards, cereal box liners, grocery bags, and other plastic food packaging. HDPE’s tensile strength, high impact resistance and melting points, and large strength-to-density ratio make it ideal for food and beverage packaging. Also, HDPE is a nonporous polymer, which allows product teams to make long-lasting and easy-to-clean parts that don’t require additional maintenance.

Although HDPE does offer resistance to mildew, mold, and insects, it has poor weathering resistance compared to other materials on this list and it isn’t resistant to oxidizing acids. HDPE is also highly flammable, prone to stress cracking, and non-biodegradable. Further, it’s difficult to bond HDPE with other food-grade plastics, which can limit design and engineering capabilities.

These limitations notwithstanding, HDPE is an excellent choice for creating FDA-approved plastic food containers. For instance, HDPE’s high heat resistance makes it dishwasher safe — an excellent feature for food packaging. Also, HDPE is non-leaching, meaning a disinfectant cleans it quickly but dissolves in time for safe human interaction. Since HDPE is resistant to most chemical solvents, it can prevent harsh chemicals from interacting with food and beverages.

Some food-grade plastics are better for packaging — they are strong, chemically resistant, and tough against stress.

Polyetheretherketone (PEEK)

PEEK is a lightweight and strong semi-crystalline thermoplastic. Due to its high melting point and low coefficient of thermal expansion, PEEK has high dimensional stability. As such, PEEK food handling products can withstand microwave use, dishwasher use, and intense temperatures when cooking directly on heat.

PEEK is safe for direct contact with delicate foods like raw lettuce or fresh dairy products even during the production process. For this reason, PEEK food handling components are used in both food packaging and food production processes. Some common products made from PEEK resin include blenders, kneaders, mixing paddles and scrapers, and valves and nozzles on coffee machines.

PEEK outpaces other food-safe plastics in terms of design flexibility. PEEK can be manufactured with added colorants to make it a vibrant color, which increases process safety since broken or damaged PEEK parts will be immediately noticeable during production. This helps prevent hazardous food and beverage consumption and accidental contamination.

Acrylic (PMMA)

PMMA is a transparent plastic that offers incredible strength and stiffness and can be optically clear. This transparency makes it easy for advanced vision systems or employees performing physical visual inspections to analyze and monitor food product quality throughout transportation.

PMMA is often used to store milk and other dairy products, oils, and feed for animals. Acrylic is also used to create mixing bowls, where transparency can aid mixing and other cooking process applications. PMMA is BPA-free and non-toxic when solid, and it’s so biocompatible that acrylic is frequently used in dentures and cavity fillings.

The limitations of acrylic include poor impact resistance and limited heat resistance, weakness against attacks by organic solvents, and susceptibility to cracking under pressure due to poor wear and abrasion defense. It’s important to consider these downsides when choosing whether or not to use PMMA for food and beverage packaging purposes.

Polypropylene (PP)

PP is a semi-crystalline thermoplastic manufactured through the polymerization of propene. PP is lightweight and moldable but still high in strength, making it an excellent FDA food-grade plastic. It also boasts a high melting point — making it safe for dishwasher and microwave use — low water absorption, and excellent chemical resistance.

Polypropylene can be translucent or opaque and matched to any color. Design teams will have endless opportunities to experiment with aesthetics using this material. Colorful PP food components can also increase process safety and help teams adhere to food safety best practices.

Although polypropylene has a high melting point, it is highly flammable and prone to thermal expansion. These characteristics limit its high-temperature applications. PP is also susceptible to UV degradation, oxidation, and damage from chlorinated solvents. Its poor bonding properties can also limit manufacturing opportunities, so be sure to consider this in your design and material selection process.

Serving up Food-Grade Plastics With SyBridge

When designing parts or products intended for food and beverage handling, consider the many kinds of plastic materials you could use. Some plastics are better for packaging — they are strong, chemically resistant, and tough against stress. Others are better for direct contact with food — they’re safe, resistant to high temperatures, and can be formed into interesting and complex shapes. You also have to weigh plastics that are transparent for visibility against those that utilize bright colors for optimal safety.

A seasoned manufacturing partner like SyBridge can help you sort through these different considerations and choose the FDA-approved plastics for food contact that are best suited to your needs. By feeling confident in your choice of food-safe plastic, you’ll be able to quickly and efficiently manufacture beautiful, high-functioning parts and projects. Contact us today to learn more about food-safe product opportunities SyBridge can offer you.

Category: Knowledge CenterTag: Consumer Goods, Materials

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Polyoxymethylene (POM), more commonly known as acetal or its branded name Delrin®, is an engineering plastic offering low friction, high stiffness, and excellent dimensional stability. Polyoxymethylene is a category of thermoplastics and includes many different formulations of the material, all of which vary slightly. As such, it’s important to learn as much as you can about each type before choosing one for your next project. Delrin® is a semi-crystalline engineering-grade thermoplastic widely used to create highly precise parts. In general, Delrin® provides impressive dimensional stability and sliding properties. It’s known for its high strength, wide operating temperature range (-40°C to 120°C), and excellent mechanical properties. Here’s everything you need to know about this material, from how it’s made to its best-fit applications. Inside the polyoxymethylene production process Acetal was first discovered by German chemist Hermann Staudinger in 1920 before it was commercially synthesized by research chemists at DuPont, the original manufacturers of Delrin® plastic, in 1956. Like all other plastics, acetal is created by distilling hydrocarbon fuels down into lighter groups called “fractions,” which can then be combined with other catalysts via polymerization or polycondensation to produce a finished plastic. To make an acetal homopolymer like Delrin®, anhydrous formaldehyde must be generated by causing a reaction between aqueous formaldehyde and alcohol to form a hemiformal. The hemiformal is then heated to release the formaldehyde, and the formaldehyde is polymerized by anionic catalysis. The resulting polymer is stabilized when it reacts with acetic anhydride, which creates polyoxymethylene homopolymer. Acetal comes in many different commercial varieties and formulations, each with its own advantages and disadvantages. For example, Delrin® 500 is medium-viscosity, all-purpose polyoxymethylene that has a good balance of flow and physical properties. It can be used to produce parts via CNC machining and injection molding and is frequently used to manufacture mechanical parts, fuel systems, and fasteners. Delrin® 1700P, on the other hand, is a very low- viscosity, fast-molding resin that is best suited for parts with complex shapes, thin walls, long flow paths, or multi-cavity tools. It also offers the best molding thermal stability for deposit-free molding in demanding conditions. Since there are dozens of different formulations of acetal, it’s important to do your research and make sure your prospective plastic offers all of the properties you need for your application. Delrin® plastic properties and mechanical specifications small black Delrin pieces Delrin® can also be found in all-purpose industrial equipment like bearings, gears, pumps, and meters. Acetal’s excellent mechanical properties make it extremely versatile, offering a unique blend of properties that you won’t find in most metals or other plastics. Delrin® plastic is strong, rigid, and resistant to impact, creep, abrasion, friction, and fatigue. It’s also well known for its excellent dimensional stability during high-precision machining. Acetal can also stand up to moisture, gasoline, solvents, and a wide range of other neutral chemicals at room temperature. From a design standpoint, parts made with extruded POM naturally have a glossy surface finish. Since acetal is compatible with CNC machining, injection molding, extrusion, compression molding, rotational casting, and more, product teams are free to choose the manufacturing process that works best for their budget and their needs. However, it’s worth noting that Delrin® plastic is typically very challenging to bond. Acetal material properties vary by formulation, but the mechanical properties for Delrin® 100 NC010, one of the most popular formulations, include: Tensile modulus: 2900 MPa Yield stress: 71 MPa Yield strain: 26% Density: 1420 kg/m3 Charpy notched impact strength, +23°C: 15 kJ/m2 Coefficient of linear thermal expansion, normal: 110 E-6/K Water absorption: 0.9% Delrin® does have a few limitations. For instance, even though Delrin® is resistant to many chemicals and solvents, it’s not very resistant to strong acids, oxidizing agents, or UV radiation. Prolonged exposure to radiation can warp the color and cause the part to lose its strength. Also, this material isn’t readily available in a flame-retardant grade, which limits its utility for certain high-temperature applications. Why choose Delrin® plastic? These limitations notwithstanding, there are many reasons to choose acetal over other materials. When compared to other plastics, acetal offers better creep, impact, and chemical resistance, better dimensional stability, and higher strength. It also has a lower coefficient of friction. Acetal outpaces certain metals as well. Parts built with this material have a higher strength-to-weight ratio, better corrosion resistance, and offer more opportunities for part consolidation. You can build thinner and lighter parts faster and at a lower price point with acetal than with a comparable metal. Delrin® plastic can be found in almost every major manufacturing sector. In the automotive industry, common applications include heavy load-bearing gears, fuel system components, loudspeaker grilles, and safety system components like seatbelt hardware. Delrin® can also be found in all-purpose industrial equipment like bearings, gears, pumps, and meters. In the consumer goods and appliances space, this material can be used to make anything from zippers and pens to knife handles and lawn sprinklers. Getting started with Delrin® There’s a lot for product teams to love about Delrin®. It’s strong, stable, versatile, and its excellent mechanical properties make it a good choice for a wide variety of applications in a number of industries. However, with dozens of different formulations of acetal on the market, it can be very challenging to determine which one might be the best fit for your unique project. A seasoned manufacturing partner can help demystify the material selection process. When you partner with Fast Radius, you partner with a team of on-demand manufacturing experts who have years of experience helping product teams navigate material selection. We’re well-versed in the wide range of materials that can be used for both traditional and additive manufacturing — including Delrin®. Once you’ve selected the Delrin® formulation that’s the right fit for your application, our team of experts can help facilitate the entire manufacturing process — from design and prototyping to production and fulfillment. With a full suite of manufacturing services including CNC machining and injection molding, Fast Radius can bring your vision to life quickly and easily. Contact us today to get started.

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