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Home / Resources / The Basics of Working with Elastomeric Materials

The Basics of Working with Elastomeric Materials

August 12, 2020 by SyBridge Technologies
Elastomerics

Originally published on fastradius.com on August 12, 2020

What do car tires, watertight gaskets, shoe soles, rubber bands, and pencil erasers all have in common? Many of these objects are things we interact with on a daily basis, but they’re also made using elastomers, or “elastic polymers.”

Elastomeric materials are pliable synthetic polymers that are similar to rubber. While the two share similar characteristics, they differ in a few key ways. Rubber, for instance, is a naturally occurring compound derived from latex. While an incredibly useful and versatile material, rubber’s chemical makeup imposes certain manufacturing limitations and also makes parts prone to ozone cracking. Elastomers, on the other hand, are a family of petroleum-based polymers that act very similarly to rubber but offer better material properties.

This article will provide a brief primer on manufacturing with elastomeric materials.

Defining characteristics and mechanical properties of elastomers

Elastomers are materials that have the ability to stretch and then rebound back to their original shape. Elastomers provide a range of other benefits, including high elasticity, abrasion and tear resistance, impermeability, soft textures, and slip resistance. They can also withstand significant temperature fluctuations and are ideal for temperature and electrical insulation.

Elastomers can be chemically tuned for a broad range of applications. For example, elastomeric materials could be tuned for improved rebound for something like a shoe sole or tuned for a low rebound, dampening product like a grip. They can also provide suction and sealing. Depending on the application, selecting the right material can improve the desired characteristics of the final part.

Thermoplastics vs. thermosets

It’s important to note that there are two primary kinds of elastomers: thermoplastics and thermosets. Thermoplastics liquify when heated and solidify when cooled — a process that can be repeated, extending the lifecycle of the material. This quality makes them especially useful for manufacturing injection-molded parts at high volume. These strong polymer materials are typically shrink-resistant, shock-absorbent, and largely recyclable, as well.

Thermoplastics

In contrast, thermoset plastics cannot be melted down and reused after the part has set. The curing process triggers a chemical reaction that incites the formation of incredibly strong three-dimensional cross-links between molecules within the polymer — the bonds are nearly impossible to break, even under extreme temperatures. Because of the high durability, strength, and warp resistance these bonds provide, thermosets are often used to reinforce other materials against impact and deformation.

Four important factors for designing and manufacturing elastomeric parts

In order to maximize the desired material properties of elastomeric parts, there are a few critical considerations that product teams would do well to keep in mind.

1. Lead with clearly-defined requirements

The specific requirements for a given application should drive material selection and design for the part. By having a clear understanding of those requirements, manufacturers can quickly determine which elastomeric material offers the most significant benefits.

Using a material requirements planning (MRP) system often proves beneficial for product teams. Working retroactively from production plans and schedules, these systems generate lists of component and material requirements that provide visibility into what materials are needed, in what quantity, and in what timeframe — all of which can help manufacturers stay on-schedule and properly resourced.

2. Achieve appropriate draft

Draft refers to tapered angles incorporated into part design that help ensure that the part is ejected smoothly from the mold. Insufficient draft not only makes the part harder to remove, but can also result in bends, breaks, warps, and inferior surface finishes as the plastic cools.

Elastomeric components typically require a significant amount of draft to prevent the material from sticking to the mold itself. Adding texture to the ejector pins to give them extra grip is another method for increasing the efficiency of removing parts from their molds.

3. Calibrate wall thickness to specific requirements

Generally, the thickness of a part’s walls should be kept  between 1.5 and 3 mm of thickness and should be as uniform as possible. This helps the part cool faster (thereby reducing cycle time), and prevents irregular shrinkage and unsightly sink marks. If a part application requires varying wall thicknesses, then a gradual transition should be incorporated to maintain design integrity.

The pliable nature of elastomeric materials allows parts to be designed with higher wall thickness as well as variations in wall thickness. By applying pressure during production, engineers can shape or form the material in ways that cannot be achieved through injection molding or when manufacturing with more rigid materials.

4. Maximize effectiveness of overmolding

Overmolding refers to the process of creating an elastomer layer that is then attached to a rigid, non-elastomeric part. One common example of this is the pliable grip found on many hand tools, which provides slip resistance and keeps the user from holding onto rigid plastic or metal — both of which improve the safety and efficiency of the tool.

To maximize the effectiveness of an overmolded grip, engineers need to design the product to enable good bond strength between the elastomeric and rigid materials through both chemical and mechanical methods. The chemical attachment in particular is important because the bonds that form between the two materials improve the durability and longevity of the part, while also removing the need for additional surface pre-treatments or adhesives.

Efficient elastomer manufacturing — and more

Elastomers are a versatile category of rubber-like thermoplastics that offer significantly improved material qualities. Thermoplastic elastomers’ unique set of chemical and physical resistances — as well as their high pliability and strength — enable manufacturers to produce many of the items we interact with everyday, including everything from bicycle inner tubes to wetsuits.

Partnering with an experienced manufacturing partner like SyBridge Technologies empowers product teams to get the most out of any material or part design. Our team of experienced, collaborative engineers and designers are as adept at talking elastomer prototyping as they are the latest processes in additive manufacturing, and we work closely with each customer to ensure that every stage of the production process is optimized for specific design, manufacturability, and timeline requirements. Contact us today and discover the attention to detail, efficiency, and cost effectiveness that SyBridge Technologies brings.

Category: Knowledge CenterTag: Materials

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Polyoxymethylene (POM), more commonly known as acetal or its branded name Delrin®, is an engineering plastic offering low friction, high stiffness, and excellent dimensional stability. Polyoxymethylene is a category of thermoplastics and includes many different formulations of the material, all of which vary slightly. As such, it’s important to learn as much as you can about each type before choosing one for your next project. Delrin® is a semi-crystalline engineering-grade thermoplastic widely used to create highly precise parts. In general, Delrin® provides impressive dimensional stability and sliding properties. It’s known for its high strength, wide operating temperature range (-40°C to 120°C), and excellent mechanical properties. Here’s everything you need to know about this material, from how it’s made to its best-fit applications. Inside the polyoxymethylene production process Acetal was first discovered by German chemist Hermann Staudinger in 1920 before it was commercially synthesized by research chemists at DuPont, the original manufacturers of Delrin® plastic, in 1956. Like all other plastics, acetal is created by distilling hydrocarbon fuels down into lighter groups called “fractions,” which can then be combined with other catalysts via polymerization or polycondensation to produce a finished plastic. To make an acetal homopolymer like Delrin®, anhydrous formaldehyde must be generated by causing a reaction between aqueous formaldehyde and alcohol to form a hemiformal. The hemiformal is then heated to release the formaldehyde, and the formaldehyde is polymerized by anionic catalysis. The resulting polymer is stabilized when it reacts with acetic anhydride, which creates polyoxymethylene homopolymer. Acetal comes in many different commercial varieties and formulations, each with its own advantages and disadvantages. For example, Delrin® 500 is medium-viscosity, all-purpose polyoxymethylene that has a good balance of flow and physical properties. It can be used to produce parts via CNC machining and injection molding and is frequently used to manufacture mechanical parts, fuel systems, and fasteners. Delrin® 1700P, on the other hand, is a very low- viscosity, fast-molding resin that is best suited for parts with complex shapes, thin walls, long flow paths, or multi-cavity tools. It also offers the best molding thermal stability for deposit-free molding in demanding conditions. Since there are dozens of different formulations of acetal, it’s important to do your research and make sure your prospective plastic offers all of the properties you need for your application. Delrin® plastic properties and mechanical specifications small black Delrin pieces Delrin® can also be found in all-purpose industrial equipment like bearings, gears, pumps, and meters. Acetal’s excellent mechanical properties make it extremely versatile, offering a unique blend of properties that you won’t find in most metals or other plastics. Delrin® plastic is strong, rigid, and resistant to impact, creep, abrasion, friction, and fatigue. It’s also well known for its excellent dimensional stability during high-precision machining. Acetal can also stand up to moisture, gasoline, solvents, and a wide range of other neutral chemicals at room temperature. From a design standpoint, parts made with extruded POM naturally have a glossy surface finish. Since acetal is compatible with CNC machining, injection molding, extrusion, compression molding, rotational casting, and more, product teams are free to choose the manufacturing process that works best for their budget and their needs. However, it’s worth noting that Delrin® plastic is typically very challenging to bond. Acetal material properties vary by formulation, but the mechanical properties for Delrin® 100 NC010, one of the most popular formulations, include: Tensile modulus: 2900 MPa Yield stress: 71 MPa Yield strain: 26% Density: 1420 kg/m3 Charpy notched impact strength, +23°C: 15 kJ/m2 Coefficient of linear thermal expansion, normal: 110 E-6/K Water absorption: 0.9% Delrin® does have a few limitations. For instance, even though Delrin® is resistant to many chemicals and solvents, it’s not very resistant to strong acids, oxidizing agents, or UV radiation. Prolonged exposure to radiation can warp the color and cause the part to lose its strength. Also, this material isn’t readily available in a flame-retardant grade, which limits its utility for certain high-temperature applications. Why choose Delrin® plastic? These limitations notwithstanding, there are many reasons to choose acetal over other materials. When compared to other plastics, acetal offers better creep, impact, and chemical resistance, better dimensional stability, and higher strength. It also has a lower coefficient of friction. Acetal outpaces certain metals as well. Parts built with this material have a higher strength-to-weight ratio, better corrosion resistance, and offer more opportunities for part consolidation. You can build thinner and lighter parts faster and at a lower price point with acetal than with a comparable metal. Delrin® plastic can be found in almost every major manufacturing sector. In the automotive industry, common applications include heavy load-bearing gears, fuel system components, loudspeaker grilles, and safety system components like seatbelt hardware. Delrin® can also be found in all-purpose industrial equipment like bearings, gears, pumps, and meters. In the consumer goods and appliances space, this material can be used to make anything from zippers and pens to knife handles and lawn sprinklers. Getting started with Delrin® There’s a lot for product teams to love about Delrin®. It’s strong, stable, versatile, and its excellent mechanical properties make it a good choice for a wide variety of applications in a number of industries. However, with dozens of different formulations of acetal on the market, it can be very challenging to determine which one might be the best fit for your unique project. A seasoned manufacturing partner can help demystify the material selection process. When you partner with Fast Radius, you partner with a team of on-demand manufacturing experts who have years of experience helping product teams navigate material selection. We’re well-versed in the wide range of materials that can be used for both traditional and additive manufacturing — including Delrin®. Once you’ve selected the Delrin® formulation that’s the right fit for your application, our team of experts can help facilitate the entire manufacturing process — from design and prototyping to production and fulfillment. With a full suite of manufacturing services including CNC machining and injection molding, Fast Radius can bring your vision to life quickly and easily. Contact us today to get started.

Know Your Materials: Delrin (Polyoxymethylene)

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