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Home / Resources / An Overview of Polypropylene Fillers

An Overview of Polypropylene Fillers

July 20, 2020 by SyBridge Technologies
polypropylene fillers

Originally published on fastradius.com on July 20, 2020

Polypropylene is a thermoplastic polymer resin that can be easily combined with other composites. This material is extremely popular among engineers, particularly for injection molding, because it is exceptionally durable and suitable for a wide variety of use-cases. Common applications include living hinges, snap fits, reusable containers, and even car batteries.

For certain projects, engineers need to add fillers to their chosen material in order to achieve the desired chemical or mechanical properties. Fillers are microscopic particles added to a resin during the manufacturing process that may make the product stronger, more flexible, cheaper to produce, or provide some other quality or set of qualities. Here’s everything you need to know about polypropylene-compatible fillers.

Different types of polypropylene fillers

The primary advantage of fillers is that they allow engineers to augment the natural properties of polypropylene to avoid jumping to the next pricing tier of materials. For example, polypropylene is one of the cheapest engineering plastics to mold and fairly pliable in comparison to acrylonitrile butadiene styrene (ABS) or nylon. Polypropylene with 30% to 50% glass fiber filler is just as stiff as base nylon, for a fraction of the cost.

The three most common types of polypropylene fillers are glass beads or glass fiber, talc or magnesium, and calcium carbonate.

Glass beads or glass fiber fillers

Glass beads are microscopic beads of glass, while glass fibers are long strands of glass. Both varieties of glass fillers are used to strengthen the mechanical properties of the substrate — providing, for instance, improved flexural modulus, stiffness, or tensile strength. Glass beads are particularly well-suited for increasing chemical resistance and chemical absorption. However, adding glass fillers to polypropylene significantly drives up production costs.

Talc or magnesium fillers

In general, engineers add talc fillers to polypropylene when they require a thickening agent. Talc allows the resin to be injected in thicker wall sections without increasing sink or warpage. Like talc, magnesium offers similar advantages when added to polypropylene.

Calcium carbonate fillers

Calcium carbonate can be used to modify the thermal properties of polypropylene, thereby increasing the operating temperature of the material or improving insulation.

3 key considerations for choosing a filler

Fillers come in handy when engineers need to add certain chemical or mechanical properties to polypropylene resin, but they’re not necessary for every use-case. When engineers start a project, they’re looking for a thermoplastic that will suit their needs without modification; fillers only come into play if this isn’t possible. Here are three key considerations for choosing a polypropylene filler.

1. Understand what the filler should do

Before deciding on a filler, product teams should have a clear understanding of what they want to accomplish. If the product needs more stiffness, glass fibers may be an appropriate choice. If they’re making a large part, talc may be best because it helps to pack out a part by increasing its density. Careful upfront planning prevents costly delays.

2. Choose a filler based on performance

Along the same lines, engineers should consider the degree to which they are trying to modify the polypropylene. If only small modifications are required, it might be advisable to choose a different material rather than go through the added effort of employing fillers.

3. Compare costs

All fillers drive up costs, so it often makes sense to avoid them altogether. For example, using 70% glass-filled polypropylene will be more expensive than nylon, but will likely provide comparable mechanical strength — in which case it would be more energy and cost-effective to go with nylon from the get-go. Before deciding to use fillers, conduct a thorough cost-benefit analysis to determine whether the same chemical and mechanical properties can be achieved through other means.

Get started with SyBridge

Glass, talc, and calcium carbonate fillers are used to enhance polypropylene’s performance. When used effectively, engineers can add fillers to this resin and achieve chemical and mechanical properties that are comparable to other high-strength materials like nylon. Fillers can be expensive, however, and they’re not suitable for every use-case. An experienced manufacturing partner can help you make sure you’re making the best decision for your project.

The SyBridge team is your one-stop-shop for manufacturing innovation. When you partner with us, you gain access to an elite team of manufacturing experts, designers, and engineers who will see you through the entire production process, from design and prototyping to fulfillment. You’ll have our global manufacturing network and years of expertise at your disposal. Ask us anything — we’re ready to help. Contact us today.

Category: Knowledge CenterTag: Materials

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Polyoxymethylene (POM), more commonly known as acetal or its branded name Delrin®, is an engineering plastic offering low friction, high stiffness, and excellent dimensional stability. Polyoxymethylene is a category of thermoplastics and includes many different formulations of the material, all of which vary slightly. As such, it’s important to learn as much as you can about each type before choosing one for your next project. Delrin® is a semi-crystalline engineering-grade thermoplastic widely used to create highly precise parts. In general, Delrin® provides impressive dimensional stability and sliding properties. It’s known for its high strength, wide operating temperature range (-40°C to 120°C), and excellent mechanical properties. Here’s everything you need to know about this material, from how it’s made to its best-fit applications. Inside the polyoxymethylene production process Acetal was first discovered by German chemist Hermann Staudinger in 1920 before it was commercially synthesized by research chemists at DuPont, the original manufacturers of Delrin® plastic, in 1956. Like all other plastics, acetal is created by distilling hydrocarbon fuels down into lighter groups called “fractions,” which can then be combined with other catalysts via polymerization or polycondensation to produce a finished plastic. To make an acetal homopolymer like Delrin®, anhydrous formaldehyde must be generated by causing a reaction between aqueous formaldehyde and alcohol to form a hemiformal. The hemiformal is then heated to release the formaldehyde, and the formaldehyde is polymerized by anionic catalysis. The resulting polymer is stabilized when it reacts with acetic anhydride, which creates polyoxymethylene homopolymer. Acetal comes in many different commercial varieties and formulations, each with its own advantages and disadvantages. For example, Delrin® 500 is medium-viscosity, all-purpose polyoxymethylene that has a good balance of flow and physical properties. It can be used to produce parts via CNC machining and injection molding and is frequently used to manufacture mechanical parts, fuel systems, and fasteners. Delrin® 1700P, on the other hand, is a very low- viscosity, fast-molding resin that is best suited for parts with complex shapes, thin walls, long flow paths, or multi-cavity tools. It also offers the best molding thermal stability for deposit-free molding in demanding conditions. Since there are dozens of different formulations of acetal, it’s important to do your research and make sure your prospective plastic offers all of the properties you need for your application. Delrin® plastic properties and mechanical specifications small black Delrin pieces Delrin® can also be found in all-purpose industrial equipment like bearings, gears, pumps, and meters. Acetal’s excellent mechanical properties make it extremely versatile, offering a unique blend of properties that you won’t find in most metals or other plastics. Delrin® plastic is strong, rigid, and resistant to impact, creep, abrasion, friction, and fatigue. It’s also well known for its excellent dimensional stability during high-precision machining. Acetal can also stand up to moisture, gasoline, solvents, and a wide range of other neutral chemicals at room temperature. From a design standpoint, parts made with extruded POM naturally have a glossy surface finish. Since acetal is compatible with CNC machining, injection molding, extrusion, compression molding, rotational casting, and more, product teams are free to choose the manufacturing process that works best for their budget and their needs. However, it’s worth noting that Delrin® plastic is typically very challenging to bond. Acetal material properties vary by formulation, but the mechanical properties for Delrin® 100 NC010, one of the most popular formulations, include: Tensile modulus: 2900 MPa Yield stress: 71 MPa Yield strain: 26% Density: 1420 kg/m3 Charpy notched impact strength, +23°C: 15 kJ/m2 Coefficient of linear thermal expansion, normal: 110 E-6/K Water absorption: 0.9% Delrin® does have a few limitations. For instance, even though Delrin® is resistant to many chemicals and solvents, it’s not very resistant to strong acids, oxidizing agents, or UV radiation. Prolonged exposure to radiation can warp the color and cause the part to lose its strength. Also, this material isn’t readily available in a flame-retardant grade, which limits its utility for certain high-temperature applications. Why choose Delrin® plastic? These limitations notwithstanding, there are many reasons to choose acetal over other materials. When compared to other plastics, acetal offers better creep, impact, and chemical resistance, better dimensional stability, and higher strength. It also has a lower coefficient of friction. Acetal outpaces certain metals as well. Parts built with this material have a higher strength-to-weight ratio, better corrosion resistance, and offer more opportunities for part consolidation. You can build thinner and lighter parts faster and at a lower price point with acetal than with a comparable metal. Delrin® plastic can be found in almost every major manufacturing sector. In the automotive industry, common applications include heavy load-bearing gears, fuel system components, loudspeaker grilles, and safety system components like seatbelt hardware. Delrin® can also be found in all-purpose industrial equipment like bearings, gears, pumps, and meters. In the consumer goods and appliances space, this material can be used to make anything from zippers and pens to knife handles and lawn sprinklers. Getting started with Delrin® There’s a lot for product teams to love about Delrin®. It’s strong, stable, versatile, and its excellent mechanical properties make it a good choice for a wide variety of applications in a number of industries. However, with dozens of different formulations of acetal on the market, it can be very challenging to determine which one might be the best fit for your unique project. A seasoned manufacturing partner can help demystify the material selection process. When you partner with Fast Radius, you partner with a team of on-demand manufacturing experts who have years of experience helping product teams navigate material selection. We’re well-versed in the wide range of materials that can be used for both traditional and additive manufacturing — including Delrin®. Once you’ve selected the Delrin® formulation that’s the right fit for your application, our team of experts can help facilitate the entire manufacturing process — from design and prototyping to production and fulfillment. With a full suite of manufacturing services including CNC machining and injection molding, Fast Radius can bring your vision to life quickly and easily. Contact us today to get started.

Know Your Materials: Delrin (Polyoxymethylene)

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